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Litharge

 
Chemical Composition | Uses
 
 

Introduction:

 
Litharge (Lead monoxide PbO) is a crystalline product with predominantly orthorhombic structure. It is commercially available as a canary yellow powder with a reddish tint. Lead monoxide, commonly known as Litharge is not only the most important oxide of lead but also the most widely used inorganic lead chemicals. It is produced in a variety of grades depending upon its specific use. Commercial Litharge is a ground yellow to Canary yellow powder. The particle size varies from a fine particle average radius of 1.5 to 8.0 microns. It occurs in two poly-morphic forms. The tetragonal from PbO (red in color) is stable upto 489°C while the orthorhombic * form (*-PbO) (Yellow in color) is stable above this temperature. Thus the difference in color is caused by the state of crystallization.
Litharge
 

It is hygroscopic in nature and tends to absorb water when coming in contact with moisture. Consequently hard lumps are formed which on drying regain its original powder form. When stored in humid conditions, a layer of white lead carbonate is formed on the surface due to contact with atmospheric carbon dioxide.

 
 
Chemical Composition:
 

Conform to IS 58: 1976

 

Color

Canary Yellow with a reddish tint

Specific gravity gm/cm3

9.5 - 9.9 (Depending upon state of crystallization)

Melting Point

897°C (It begins to sublime before melting)

Solubility in water gm/litre

0.10

Thermal Stability

250°C/ 897°C

Apparent (scott) Density gm/cc

1.8 - 2.2

Retention on 63 micron IS Sieve % Max

0.1Max

Water absorption mgs/gm

90 to 110

Acid absorption mgs/gm

80 to 110

Petrol Subsidence mgs/gm

0.40 to 0.42

Volatile matter (at 102DC% Max)

0.1

Insoluble in Acetic Acid % Max

0.08

Solution in nitric Acid

Clear

Free Lead % Max

0.01%

Red Lead (Pb3O4) % Max

0.03% Max

Other Impurities (Elemental) % Max

0.003

PbO Contents %

99.9

Packing

 

 

(a) 1 ton Jumbo bag

 

(b) 25 Kg net in polythene lined Hessian Bags or

 

     HDPE bags with inner polythene packing

 

(c) As per Customer's Specification.

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Uses:
 

Storage battery: Plates for electric storage batteries consume the major quantity of Litharge. Pure Litharge alone or mixed with red lead or mixed with lead suboxide and red lead is used in heavy duty batteries and in batteries requiring extra long life.

USES (Litharge Chemical Grade):

Ceramic and glass industry: For manufacture of glass of high lead content having higher density, lower thermal conductivity, higher index of refraction, greater brilliance, stability and toughness than other glass.

Glazes and vitreous enamels: These are the glossy coatings used to protect ceramic bodies. Lead monoxide is one of the major raw materials for glazes. Vitreous enamels for metals are often formulated with litharge, chiefly for coating cast iron. Ferroelectric ceramics are prepared by fusing litharge with numerous other metallic oxides.

High Temperatures lubricant and greases: Lead monoxide effectively reduces the friction of metals in sliding contact with each other at temperatures up to 675°C.

Insecticides: Litharge is the primary material in the manufacture of lead Arsenate.

Inorganic Pigments: Litharge is used as a basic material in the manufacture of lead silicates, while white lead and lead is used for manufacturing of chromate pigments

Lead Soaps: Lead soaps widely used as driers in varnishes are made from litharge and organic acids.

Petroleum refining: Litharge is used in alkaline solution as sodium plumbite to convert meracaptans and free sulfur to disulfides

Rubber Industry: Litharge accelerates the curing rate and search time of rubber and is often used with other accelerators as well as an activator, chiefly in natural styrene- butadiene and nitrite rubbers. It is also used as a vulcanizing agent for chloroprene and polyethylacrylate rubbers.

Stabilizers for PVC: Litharge is the major active ingredient in the preparation of lead stabilizers for PVC. Superfine variety is also used as a stabilizer.

Miscellaneous uses: Glycerin, cement linoleum medicines and lead based chemicals require litharge as one of the primary materials.
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